The Chemicals are set to follow their headline set at T in the Park at next month's V festival
The Chemical Brothers are adding two new tracks to a forthcoming 'best of' collection.
Brotherhood is to include Midnight Madness and Keep My Composure which features an appearance by Baltimore electro rapper Spank Rock.
The other 13 tracks chart Tom and Ed Chemical's 16 year career and include classics like Hey Boy, Hey Girl, Out of Control and Galvanize.
Eight of the tracks appeared on their last compliation album, Singles 93-03.
A second disc will feature the DJs' Electronic Battle Weapons series of music experiments.
The album is set for release on 1 September to coincide with Chemical Brothers' gig at the Olympia on 30 August.
The Chemicals are the first band to play the London venue in 10 years.
They are also playing the V festivals in Staffordshire and Chelmsford on 16-17 August.
Brotherhood track listing: - Galvanize
- Hey Boy, Hey Girl
- Block Rockin' Beats
- Do It Again
- Believe
- Star Guitar
- Let Forever Be
- Leave Home
- Keep My Composure
- Saturate
- Out Of Control
- Midnight Madness
- The Golden Path
- Setting Sun
- Chemical Beats
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