They used to be called The Wildbunch and had a bit of success back in 1996.
But they'll have to work hard to beat Girls Aloud, who've managed to hold onto the top spot for three weeks, despite competition from One True Voice and The Cheeky Girls.
However, a chart expert from HMV said it was still unlikely Electric Six would go straight in at number one. But they're pretty likely to get somewhere in the top three.