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Not all analysts are convinced that the deal is the solution to the industry's troubles
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The creation of Air France-KLM will form an aviation giant with annual revenue of about 19.2bn euros (£13.4bn; $22.4bn), overtaking British Airways and Germany's Lufthansa.
The deal will reshape the future of the aviation industry and create the world's third largest airline in terms of traffic after the two biggest US carriers.
But passengers are unlikely to notice much difference as KLM and Air France will continue as separate operating companies with their own brand identities.
Money trouble
Consolidation of the airline industry has been expected for some time as many of the world's largest carriers are struggling with heavy losses.
The airlines compared (2002)
Air France
Air France chairman Jean-Cyril Spinetta said the industry had become too fragmented and not sufficiently profitable.
"The time has come to change," he told a news conference on Tuesday.
KLM chief Leo van Wijk said the partnership would secure a sustainable future for the Dutch company, which has been in financial difficulty for some time.
It has already made several failed attempts to merge with British Airways, and walked away at the last minute from a deal with Alitalia in 2000, and has been negotiating with Air France for more than a year.
KLM and Air France will be placed under a new common holding company, after a share swap agreement that values the Dutch company at 784m euros and leaves Air France as the dominant partner.
KLM shares rose 19% following the announcement but Air France stock fell by 4.6%, as investors worried that the Dutch airline would hamper rather than help Air France.
State sell-offs
KLM ran up losses of 271m euros last year, whereas Air France made an 111m euros profit.
KLM's search for a partner
Although the tie-up is effectively a takeover by Air France, the airlines will retain their separate identities because of bilateral aviation agreements between their governments and third countries which dictate where airlines can fly.
The European Commission has won a mandate to negotiate with the US to replace all these bilateral transatlantic agreements with a single pan-European deal, and analysts expect more mergers once these rules are modified.
Under the terms of the deal, the French Government's 54.4% stake in Air France will be diluted to 44% in the new company.
Alitalia, which is 62% controlled by the Italian state, is likely to be able to join Air France-KLM only after further privatisation, industry sources said.
The deal
Air France will offer 11 of its shares plus 10 Air France warrants for every 10 KLM shares.
Three warrants give the holder the right to buy two Air France shares at 20 euros apiece after 18 months.
The deal, effectively a takeover by Air France, values KLM at 784m euros - a 40% premium over KLM's stock market value at the close of trade on Monday.
Air France shareholders will own 81% of the combined company while KLM shareholders will have 19%.
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