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Firefighters have attended a fire at a Black Country kiln where a cylinder exploded during the blaze.
The fire began at about 2000 GMT at PBA Heat Treatment on Bevan Road in Brierley Hill.
About an hour later a cylinder containing ammonia exploded and a firefighter was hit by debris from the blast but did not require treatment.
Six people had to be rescued from the scene and firefighters expect to remain there throughout Thursday.
A spokesman said there had been fears that another cylinder, containing acetylene, could also explode.
He added: "Acetylene is a nasty kind of explosive which is very reactive and takes 24 hours to make sure it isn't a fire risk any more."
The ambulance service said the explosion was heard up to a mile away and a search and rescue team was called in but later stood down.
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