The accident happened just before 0800 GMT on Wednesday.
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Part of the M4 in South Gloucestershire has reopened after liquid propane gas began leaking onto the carriageway when two vehicles collided.
It is thought a goods vehicle carrying the cylinders collided with a van just before 0800 GMT on Wednesday.
Initially police put a 300m (330 yards) cordon around the incident but re-opened the motorway about 1030 GMT.
For a time slip roads onto the M4 from the M5 were closed and the motorway shut between junctions 19 and 20.
Traffic in the area is still reported to be heavy.
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