The Church's mission and evangelisation, human sexuality, social justice, the environment and violence against women will also be discussed.
The debate about homosexuality in the Anglican Church has followed the consecration in the US of the openly gay Bishop of New Hampshire, the Rt Rev Gene Robinson.
Bishop Robinson will be present on the fringes of the conference, which is being held at the University of Kent.
The controversy over his appointment led Dr Williams not to invite him.
Those boycotting the conference include the Anglican leaders of Nigeria, Rwanda, Kenya, Uganda and a group of countries in southern South America.
The Archbishop of Nigeria, Peter Akinola, told the BBC that with their support of homosexual clergy, the leaders of the global Church had broken away from the Anglican family.
While faiths exist, those in the UK must start to reflect the laws of the country in which they exist and gays and women hold as much right to practise a faith as any other human being.
He said: "Rather than make a mockery of the holy Eucharist or the sacrament of the Lord, it was better we don't participate and all efforts to get us back are failed.
"So until there is restoration of communion there is no basis for coming together."
The head of Kenya's 2.5 million Anglicans is Archbishop Benjamin Nzimbi.
He was asked by BBC News if he still saw Dr Williams as the head of the Anglican Church.
He said: "He's at the head of the Anglican Church but not necessarily the one to define Anglicans.
"When we are together with him he should be [our spiritual leader] but when he is not following what is right, he isn't."
The most senior Church of England figure not attending is the Bishop of Rochester, the Rt Rev Michael Nazir-Ali.
His non-attendance is in protest at the presence of those who have supported Bishop Robinson.
In a statement in June, he said: "Those who have gone against Church teaching should not attend representative Anglican gatherings".
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